| Cover Picture: On the Formation of Intermetalloid Clusters: Titanocene(III)diammin as a Versatile Reactant Toward Nonastannide Zintl Clusters (Angew. Chem. Int. Ed. 2/2015) Dr. Christian B. Benda, Dr. Markus Waibel and Prof. Dr. Thomas F. Fässler 365  |
| Full: PDF (652 K) |
| Inside Cover: Benzoxazolone Carboxamides: Potent and Systemically Active Inhibitors of Intracellular Acid Ceramidase (Angew. Chem. Int. Ed. 2/2015) Dr. Daniela Pizzirani, Dr. Anders Bach, Dr. Natalia Realini, Dr. Andrea Armirotti, Dr. Luisa Mengatto, Dr. Inga Bauer, Dr. Stefania Girotto, Dr. Chiara Pagliuca, Dr. Marco De Vivo, Dr. Maria Summa, Dr. Alison Ribeiro and Prof. Daniele Piomelli 366  |
| Full: PDF (2569 K) |
| Inside Back Cover: Membranes with Fast and Selective Gas-Transport Channels of Laminar Graphene Oxide for Efficient CO2 Capture (Angew. Chem. Int. Ed. 2/2015) Jie Shen, Dr. Gongping Liu, Kang Huang, Prof. Wanqin Jin, Prof. Kueir-Rarn Lee and Prof. Nanping Xu 697  |
| Full: PDF (1319 K) |
| Back Cover: A General One-Pot Strategy for the Synthesis of High-Performance Transparent-Conducting-Oxide Nanocrystal Inks for All-Solution-Processed Devices (Angew. Chem. Int. Ed. 2/2015) Jizhong Song, Sergei A. Kulinich, Jianhai Li, Yanli Liu and Prof. Haibo Zeng 698  |
| Full: PDF (734 K) |
| Graphical Abstract: Angew. Chem. Int. Ed. 2/2015 369-385 |
| Full: PDF (8046 K) |
| Spotlights on our sister journals: Angew. Chem. Int. Ed. 2/2015 388-391  |
| Full: PDF (1807 K) |
| Michael S. Sherburn 392  |
| Full: PDF (245 K) |
| Grupo Especializado de Química Organometálica Prizes 2014: J. Lloret-Fillol, E. Fernández, and J. Forniés / Hans G. A. Hellmann Prize: C. Jacob 393  |
| Full: PDF (415 K) |
| A New Era for ab initio Molecular Crystal Lattice Energy Prediction Prof. Gregory J. O. Beran 396-398  |
| Full: PDF (348 K) |
| Cascade Reactions: A Driving Force in Akuammiline Alkaloid Total Synthesis Joel M. Smith, Jesus Moreno, Ben W. Boal and Prof. Neil K. Garg 400-412  |
| Full: PDF (1020 K) |
| Selective Carbon–Carbon Bond Cleavage for the Stereoselective Synthesis of Acyclic Systems Prof. Dr. Ilan Marek, Dr. Ahmad Masarwa, Dr. Pierre-Olivier Delaye and Dr. Markus Leibeling 414-429  |
| Full: PDF (1956 K) |
| Photochromic Metal–Organic Frameworks: Reversible Control of Singlet Oxygen Generation Jihye Park, Dawei Feng, Shuai Yuan and Prof. Dr. Hong-Cai Zhou 430-435  |
| Full: PDF (1824 K) |
| Liquid-Free Lithium–Oxygen Batteries Moran Balaish, Prof. Emanuel Peled, Prof. Diana Golodnitsky and Prof. Yair Ein-Eli 436-440  |
| Full: PDF (841 K) |
| A Noncanonical Function of Sortase Enables Site-Specific Conjugation of Small Molecules to Lysine Residues in Proteins Joseph J. Bellucci, Dr. Jayanta Bhattacharyya and Prof. Ashutosh Chilkoti 441-445  |
| Full: PDF (1114 K) |
| Concatenated Logic Circuits Based on a Three-Way DNA Junction: A Keypad-Lock Security System with Visible Readout and an Automatic Reset Function Dr. Junhua Chen, Prof. Dr. Shungui Zhou and Junlin Wen 446-450  |
| Full: PDF (1578 K) |
| Profiling of Ribose Methylations in RNA by High-Throughput Sequencing Ulf Birkedal, Mikkel Christensen-Dalsgaard, Nicolai Krogh, Radhakrishnan Sabarinathan, Jan Gorodkin and Prof. Henrik Nielsen 451-455  |
| Full: PDF (1381 K) |
| Modulating the Binding of Polycyclic Aromatic Hydrocarbons Inside a Hexacationic Cage by Anion–π Interactions Dr. Nema Hafezi, Dr. James M. Holcroft, Dr. Karel J. Hartlieb, Edward J. Dale, Dr. Nicolaas A. Vermeulen, Charlotte L. Stern, Dr. Amy A. Sarjeant and Prof. J. Fraser Stoddart 456-461  |
| Full: PDF (1734 K) |
| A General One-Pot Strategy for the Synthesis of High-Performance Transparent-Conducting-Oxide Nanocrystal Inks for All-Solution-Processed Devices Jizhong Song, Sergei A. Kulinich, Jianhai Li, Yanli Liu and Prof. Haibo Zeng 462-466  |
| Full: PDF (2213 K) |
| Structure and Dynamics of Oligonucleotides in the Gas Phase Dr. Annalisa Arcella, Dr. Jens Dreyer, Dr. Emiliano Ippoliti, Ivan Ivani, Dr. Guillem Portella, Dr. Valérie Gabelica, Prof. Dr. Paolo Carloni and Prof. Dr. Modesto Orozco 467-471  |
| Full: PDF (2738 K) |
| Terminal Phosphanido Rhodium Complexes Mediating Catalytic P-P and P-C Bond Formation Ana M. Geer, Ángel L. Serrano, Prof. Bas de Bruin, Prof. Miguel A. Ciriano and Dr. Cristina Tejel 472-475  |
| Full: PDF (567 K) |
| Biocompatible Infinite-Coordination-Polymer Nanoparticle–Nucleic-Acid Conjugates for Antisense Gene Regulation Colin M. Calabrese, Dr. Timothy J. Merkel, William E. Briley, Pratik S. Randeria, Suguna P. Narayan, Dr. Jessica L. Rouge, Dr. David A. Walker, Alexander W. Scott and Prof. Chad A. Mirkin 476-480  |
| Full: PDF (1333 K) |
| Cell-Derived Vesicles for Single-Molecule Imaging of Membrane Proteins Faruk H. Moonschi, Amy K. Effinger, Xiaolu Zhang, William E. Martin, Ashley M. Fox, Dr. David K. Heidary, Prof. Jason E. DeRouchey and Prof. Christopher I. Richards 481-484  |
| Full: PDF (1977 K) |
| Benzoxazolone Carboxamides: Potent and Systemically Active Inhibitors of Intracellular Acid Ceramidase Dr. Daniela Pizzirani, Dr. Anders Bach, Dr. Natalia Realini, Dr. Andrea Armirotti, Dr. Luisa Mengatto, Dr. Inga Bauer, Dr. Stefania Girotto, Dr. Chiara Pagliuca, Dr. Marco De Vivo, Dr. Maria Summa, Dr. Alison Ribeiro and Prof. Daniele Piomelli 485-489  |
| Full: PDF (854 K) |
| Design and Synthesis of High-Affinity Dimeric Inhibitors Targeting the Interactions between Gephyrin and Inhibitory Neurotransmitter Receptors Dr. Hans Michael Maric, Vikram Babu Kasaragod, Dr. Linda Haugaard-Kedström, Dr. Torben Johann Hausrat, Prof. Dr. Matthias Kneussel, Prof. Dr. Hermann Schindelin and Prof. Dr. Kristian Strømgaard 490-494  |
| Full: PDF (1213 K) |
| Synthesis and Structure of LaSc2N@Cs(hept)-C80 with One Heptagon and Thirteen Pentagons Dr. Yang Zhang, Kamran B. Ghiassi, Qingming Deng, Nataliya A. Samoylova, Prof. Marilyn M. Olmstead, Prof. Alan L. Balch and Dr. Alexey A. Popov 495-499  |
| Full: PDF (1513 K) |
| Peptide-Induced Hierarchical Long-Range Order and Photocatalytic Activity of Porphyrin Assemblies Dr. Kai Liu, Ruirui Xing, Dr. Chengjun Chen, Dr. Guizhi Shen, Dr. Linyin Yan, Dr. Qianli Zou, Prof. Dr. Guanghui Ma, Prof. Dr. Helmuth Möhwald and Prof. Dr. Xuehai Yan 500-505  |
| Full: PDF (1943 K) |
| Direct Cytosolic Delivery of siRNA Using Nanoparticle-Stabilized Nanocapsules Ying Jiang, Rui Tang, Bradley Duncan, Ziwen Jiang, Dr. Bo Yan, Rubul Mout and Prof. Dr. Vincent M. Rotello 506-510  |
| Full: PDF (1161 K) |
| Rational Design of Heterodimeric Protein using Domain Swapping for Myoglobin Prof. Ying-Wu Lin, Dr. Satoshi Nagao, Mohan Zhang, Dr. Yasuhito Shomura, Prof. Yoshiki Higuchi and Prof. Shun Hirota 511-515  |
| Full: PDF (978 K) |
| MnTaO2N: Polar LiNbO3-type Oxynitride with a Helical Spin Order Dr. Cédric Tassel, Yoshinori Kuno, Yoshihiro Goto, Dr. Takafumi Yamamoto, Dr. Craig M. Brown, Dr. James Hester, Dr. Koji Fujita, Dr. Masanobu Higashi, Prof. Ryu Abe, Prof. Katsuhisa Tanaka, Dr. Yoji Kobayashi and Prof. Hiroshi Kageyama 516-521  |
| Full: PDF (1182 K) |
| On the Formation of Intermetalloid Clusters: Titanocene(III)diammin as a Versatile Reactant Toward Nonastannide Zintl Clusters Dr. Christian B. Benda, Dr. Markus Waibel and Prof. Dr. Thomas F. Fässler 522-526  |
| Full: PDF (943 K) |
| Spherical Nucleic Acid Nanoparticle Conjugates Enhance G-Quadruplex Formation and Increase Serum Protein Interactions Alyssa B. Chinen, Chenxia M. Guan and Prof. Chad A. Mirkin 527-531  |
| Full: PDF (1222 K) |
| Low-Temperature N2 Binding to Two-Coordinate L2Fe0 Enables Reductive Trapping of L2FeN2− and NH3 Generation Dr. Gaël Ung and Prof. Jonas C. Peters 532-535  |
| Full: PDF (634 K) |
| ZnO-Functionalized Upconverting Nanotheranostic Agent: Multi-Modality Imaging-Guided Chemotherapy with On-Demand Drug Release Triggered by pH Yinghui Wang, Shuyan Song, Jianhua Liu, Dapeng Liu and Prof. Hongjie Zhang 536-540  |
| Full: PDF (1995 K) |
| Structure of Framework Aluminum Lewis Sites and Perturbed Aluminum Atoms in Zeolites as Determined by 27Al{1H} REDOR (3Q) MAS NMR Spectroscopy and DFT/Molecular Mechanics Dr. Jiří Brus, Libor Kobera, Dr. Wolfgang Schoefberger, Dr. Martina Urbanová, Petr Klein, Dr. Petr Sazama, Dr. Edyta Tabor, Dr. Stepan Sklenak, Dr. Anna V. Fishchuk and Dr. Jiří Dědeček 541-545  |
| Full: PDF (832 K) |
| Threading Chalcogenide Layers with Polymer Chains Dr. Wei-Wei Xiong, Jianwei Miao, Dr. Kaiqi Ye, Prof. Dr. Yue Wang, Prof. Dr. Bin Liu and Prof. Dr. Qichun Zhang 546-550  |
| Full: PDF (1559 K) |
| Surfing π Clouds for Noncovalent Interactions: Arenes versus Alkenes Dr. Abil E. Aliev, Dr. Josephine R. T. Arendorf, Dr. Ilias Pavlakos, Dr. Rafael B. Moreno, Dr. Michael J. Porter, Prof. Henry S. Rzepa and Prof. William B. Motherwell 551-555  |
| Full: PDF (864 K) |
| W2466.48 Opens a Gate for a Continuous Intrinsic Water Pathway during Activation of the Adenosine A2A Receptor Dr. Shuguang Yuan, Dr. Zhenquan Hu, Prof. Slawomir Filipek and Prof. Horst Vogel 556-559  |
| Full: PDF (1204 K) |
| Ligand-Detected Relaxation Dispersion NMR Spectroscopy: Dynamics of preQ1–RNA Binding Mag. Thomas Moschen, Mag. Christoph Hermann Wunderlich, Mag. Romana Spitzer, Mag. Jasmin Levic, Dr. Ronald Micura, Dr. Martin Tollinger and Dr. Christoph Kreutz 560-563  |
| Full: PDF (708 K) |
| C-H Bond Activation by Metal–Superoxo Species: What Drives High Reactivity? Azaj Ansari, Dr. Prabha Jayapal and Prof. Gopalan Rajaraman 564-568  |
| Full: PDF (696 K) |
| Magnet Design by Integration of Layer and Chain Magnetic Systems in a π-Stacked Pillared Layer Framework Hiroki Fukunaga and Prof. Dr. Hitoshi Miyasaka 569-573  |
| Full: PDF (1816 K) |
| A Rod-Packing Microporous Hydrogen-Bonded Organic Framework for Highly Selective Separation of C2H2/CO2 at Room Temperature Peng Li, Dr. Yabing He, Dr. Yunfeng Zhao, Prof. Dr. Linhong Weng, Dr. Hailong Wang, Prof. Dr. Rajamani Krishna, Prof. Dr. Hui Wu, Prof. Dr. Wei Zhou, Prof. Dr. Michael O'Keeffe, Prof. Dr. Yu Han and Prof. Dr. Banglin Chen 574-577  |
| Full: PDF (850 K) |
| Membranes with Fast and Selective Gas-Transport Channels of Laminar Graphene Oxide for Efficient CO2 Capture Jie Shen, Dr. Gongping Liu, Kang Huang, Prof. Wanqin Jin, Prof. Kueir-Rarn Lee and Prof. Nanping Xu 578-582  |
| Full: PDF (1204 K) |
| A Two-in-one Pincer Ligand and its Diiron(II) Complex Showing Spin State Switching in Solution through Reversible Ligand Exchange Dr. Subhas Samanta, Dr. Serhiy Demesko, Dr. Sebastian Dechert and Prof. Dr. Franc Meyer 583-587  |
| Full: PDF (637 K) |
| Synthesis of Nitrogen-Doped Mesoporous Carbon Spheres with Extra-Large Pores through Assembly of Diblock Copolymer Micelles Jing Tang, Dr. Jian Liu, Dr. Cuiling Li, Yunqi Li, Prof. Moses O. Tade, Prof. Sheng Dai and Prof. Yusuke Yamauchi 588-593  |
| Full: PDF (1171 K) |
| HyperBIRD: A Sensitivity-Enhanced Approach to Collecting Homonuclear-Decoupled Proton NMR Spectra Dr. Kevin J. Donovan and Prof. Lucio Frydman 594-598  |
| Full: PDF (478 K) |
| Harnessing the Oxidation Susceptibility of Deubiquitinases for Inhibition with Small Molecules Shimrit Ohayon, Maya Refua, Adi Hendler, Prof. Amir Aharoni and Prof. Ashraf Brik 599-603  |
| Full: PDF (597 K) |
| Reversing the Stereoselectivity of a Palladium-Catalyzed O-Glycosylation through an Inner-Sphere or Outer-Sphere Pathway Shaohua Xiang, Kim Le Mai Hoang, Jingxi He, Yu Jia Tan and Prof. Dr. Xue-Wei Liu 604-607  |
| Full: PDF (538 K) |
| Metal-Free Radical 5-exo-dig Cyclizations of Phenol-Linked 1,6-Enynes for the Synthesis of Carbonylated Benzofurans Ming Hu, Dr. Ren-Jie Song and Prof. Dr. Jin-Heng Li 608-612  |
| Full: PDF (629 K) |
| Copper-Catalyzed Stereoselective Aminoboration of Bicyclic Alkenes Ryosuke Sakae, Dr. Koji Hirano, Prof. Dr. Tetsuya Satoh and Prof. Dr. Masahiro Miura 613-617  |
| Full: PDF (423 K) |
| High-Performance, Stretchable, Wire-Shaped Supercapacitors Dr. Tao Chen, Dr. Rui Hao, Prof. Huisheng Peng and Prof. Liming Dai 618-622  |
| Full: PDF (1018 K) |
| A Highly cis-Selective and Enantioselective Metal-Free Hydrogenation of 2,3-Disubstituted Quinoxalines Zhenhua Zhang and Prof. Dr. Haifeng Du 623-626  |
| Full: PDF (420 K) |
| Total Synthesis and Structural Revision of (+)-Uprolide G Acetate Liangyu Zhu, Yuan Liu, Renze Ma and Prof. Dr. Rongbiao Tong 627-632  |
| Full: PDF (658 K) |
| Ligand-Controlled Regiodivergent Nickel-Catalyzed Annulation of Pyridones Dr. Pavel A. Donets and Prof. Dr. Nicolai Cramer 633-637  |
| Full: PDF (508 K) |
| AgF-Mediated Fluorinative Cross-Coupling of Two Olefins: Facile Access to α-CF3 Alkenes and β-CF3 Ketones Dr. Bing Gao, Dr. Yanchuan Zhao and Prof. Dr. Jinbo Hu 638-642  |
| Full: PDF (484 K) |
| A Twist-Bend Nematic Phase Driven by Hydrogen Bonding Suzanne M. Jansze, Dr. Alfonso Martínez-Felipe, Prof. John M. D. Storey, Dr. Antonius T. M. Marcelis and Prof. Corrie T. Imrie 643-646  |
| Full: PDF (1012 K) |
| Asymmetric Dearomatization of β-Naphthols through an Amination Reaction Catalyzed by a Chiral Phosphoric Acid Shou-Guo Wang, Dr. Qin Yin, Dr. Chun-Xiang Zhuo and Prof. Dr. Shu-Li You 647-650  |
| Full: PDF (428 K) |
| Highly Enantioselective Intramolecular 1,3-Dipolar Cycloaddition: A Route to Piperidino-Pyrrolizidines Dr. Srinivasa Rao Vidadala, Christopher Golz, Prof. Dr. Carsten Strohmann, Dr. Constantin-G. Daniliuc and Prof. Dr. Herbert Waldmann 651-655  |
| Full: PDF (415 K) |
| Oxidative Enantioselective α-Fluorination of Aliphatic Aldehydes Enabled by N-Heterocyclic Carbene Catalysis Fangyi Li, Zijun Wu and Prof. Dr. Jian Wang 656-659  |
| Full: PDF (567 K) |
| N-Heterocyclic Carbene Catalyzed Enantioselective α-Fluorination of Aliphatic Aldehydes and α-Chloro Aldehydes: Synthesis of α-Fluoro Esters, Amides, and Thioesters Dr. Xiuqin Dong, Dr. Wen Yang, Dr. Weimin Hu and Prof. Dr. Jianwei Sun 660-663  |
| Full: PDF (380 K) |
| Photoelectrochemical Hydrogen Production in Alkaline Solutions Using Cu2O Coated with Earth-Abundant Hydrogen Evolution Catalysts Carlos G. Morales-Guio, Laurent Liardet, Dr. Matthew T. Mayer, Dr. S. David Tilley, Prof. Dr. Michael Grätzel and Prof. Dr. Xile Hu 664-667  |
| Full: PDF (962 K) |
| A Mixed Arsenic–Phosphorus Centered Biradicaloid Alexander Hinz, Prof. Dr. Axel Schulz and Dr. Alexander Villinger 668-672  |
| Full: PDF (570 K) |
| Ion-Selective Formation of a Guanine Quadruplex on DNA Origami Structures Lydia Olejko, Dr. Piotr J. Cywinski and Prof. Dr. Ilko Bald 673-677  |
| Full: PDF (480 K) |
| Chemical Assembly Systems: Layered Control for Divergent, Continuous, Multistep Syntheses of Active Pharmaceutical Ingredients Dr. Diego Ghislieri, Dr. Kerry Gilmore and Prof. Dr. Peter H. Seeberger 678-682  |
| Full: PDF (652 K) |
| Phosphide Delivery to a Cyclotrisilene Dr. Thomas P. Robinson, Dr. Michael J. Cowley, Prof. Dr. David Scheschkewitz and Prof. Dr. Jose M. Goicoechea 683-686  |
| Full: PDF (429 K) |
| Ionic Liquids: Not only Structurally but also Dynamically Heterogeneous Zhuan-Ping Zheng, Prof. Wen-Hui Fan, Soham Roy, Dr. Kamila Mazur, Andreas Nazet, Prof. Richard Buchner, Prof. Mischa Bonn and Dr. Johannes Hunger 687-690  |
| Full: PDF (678 K) |
| Enantiotopos-Selective C-H Oxygenation Catalyzed by a Supramolecular Ruthenium Complex Dr. James R. Frost, Prof. Dr. Stefan M. Huber, Dr. Stefan Breitenlechner, M. Sc. Christoph Bannwarth and Prof. Dr. Thorsten Bach 691-695  |
| Full: PDF (633 K) |