Spotlights
| Spotlights on Recent JACS Publications ACS Contributing Correspondents 10173-10173  |
| Full: PDF (126 K) |
Perspectives
| Polymerization-Induced Self-Assembly of Block Copolymer Nano-objects via RAFT Aqueous Dispersion Polymerization Nicholas J. Warren and Steven P. Armes 10174-10185  |
| Full: PDF (9007 K) |
Communications
| Mixing, Diffusion, and Percolation in Binary Supported Membranes Containing Mixtures of Lipids and Amphiphilic Block Copolymers Douglas L. Gettel, Jeremy Sanborn, Mira A. Patel, Hans-Peter de Hoog, Bo Liedberg, Madhavan Nallani, and Atul N. Parikh 10186-10189  |
| Full: PDF (1881 K) |
| Elucidation of the Cryptic Epimerase Activity of Redox-Inactive Ketoreductase Domains from Modular Polyketide Synthases by Tandem Equilibrium Isotope Exchange Ashish Garg, Xinqiang Xie, Adrian Keatinge-Clay, Chaitan Khosla, and David E. Cane 10190-10193  |
| Full: PDF (769 K) |
| Small Circular DNA Molecules Act as Rigid Motifs To Build DNA Nanotubes Hongning Zheng, Minyu Xiao, Qin Yan, Yinzhou Ma, and Shou-Jun Xiao 10194-10197  |
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| Water Oxidation by a Nickel-Glycine Catalyst Dong Wang, Giovanna Ghirlanda, and James P. Allen 10198-10201  |
| Full: PDF (632 K) |
| Copper-Catalyzed Intermolecular Trifluoromethylarylation of Alkenes: Mutual Activation of Arylboronic Acid and CF3+ Reagent Fei Wang, Dinghai Wang, Xin Mu, Pinhong Chen, and Guosheng Liu 10202-10205  |
| Full: PDF (1128 K) |
| Synthesis of Structurally Ordered Pt3Ti and Pt3V Nanoparticles as Methanol Oxidation Catalysts Zhiming Cui, Hao Chen, Mengtian Zhao, Daniel Marshall, Yingchao Yu, Héctor Abruña, and Francis J DiSalvo 10206-10209  |
| Full: PDF (1604 K) |
| Synthesis of the Rosette-Inducing Factor RIF-1 and Analogs Christine Beemelmanns, Arielle Woznica, Rosanna A. Alegado, Alexandra M. Cantley, Nicole King, and Jon Clardy 10210-10213  |
| Full: PDF (860 K) |
| Polycondensation of Polymer Brushes via DNA Hybridization Xueguang Lu, Eleanor Watts, Fei Jia, Xuyu Tan, and Ke Zhang 10214-10217  |
| Full: PDF (2582 K) |
| New Chemistry from an Old Reagent: Mono- and Dinuclear Macrocyclic Uranium(III) Complexes from [U(BH4)3(THF)2] Polly L. Arnold, Charlotte J. Stevens, Joy H. Farnaby, Michael G. Gardiner, Gary S. Nichol, and Jason B. Love 10218-10221  |
| Full: PDF (678 K) |
| Shape-Dependent Hydrogen-Storage Properties in Pd Nanocrystals: Which Does Hydrogen Prefer, Octahedron (111) or Cube (100)? Guangqin Li, Hirokazu Kobayashi, Shun Dekura, Ryuichi Ikeda, Yoshiki Kubota, Kenichi Kato, Masaki Takata, Tomokazu Yamamoto, Syo Matsumura, and Hiroshi Kitagawa 10222-10225  |
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| A Multi-iron System Capable of Rapid N2 Formation and N2 Cleavage K. Cory MacLeod, David J. Vinyard, and Patrick L. Holland 10226-10229  |
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| NO2– Activation and Reduction to NO by a Nonheme Fe(NO2)2 Complex Brian C. Sanders, Sayed M. Hassan, and Todd C. Harrop 10230-10233  |
| Full: PDF (379 K) |
| Lewis Acid-Assisted Formic Acid Dehydrogenation Using a Pincer-Supported Iron Catalyst Elizabeth A. Bielinski, Paraskevi O. Lagaditis, Yuanyuan Zhang, Brandon Q. Mercado, Christian Würtele, Wesley H. Bernskoetter, Nilay Hazari, and Sven Schneider 10234-10237  |
| Full: PDF (356 K) |
| Transition-Metal-Free Controlled Polymerization of 2-Perfluoroaryl-5-trimethylsilylthiophenes Takanobu Sanji and Tomokazu Iyoda 10238-10241  |
| Full: PDF (518 K) |
| Environmentally Benign Synthesis of Ultrathin Metal Telluride Nanowires Haoran Yang, Scott W. Finefrock, Jonatan D. Albarracin Caballero, and Yue Wu 10242-10245  |
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| Photorelaxation Induced by Water–Chromophore Electron Transfer Mario Barbatti 10246-10249  |
| Full: PDF (893 K) |
| Remote Control of Axial Chirality: Aminocatalytic Desymmetrization of N-Arylmaleimides via Vinylogous Michael Addition Nicola Di Iorio, Paolo Righi, Andrea Mazzanti, Michele Mancinelli, Alessia Ciogli, and Giorgio Bencivenni 10250-10253  |
| Full: PDF (415 K) |
| Arm-Cleavable Microgel Star Polymers: A Versatile Strategy for Direct Core Analysis and Functionalization Takaya Terashima, Saki Nishioka, Yuta Koda, Mikihito Takenaka, and Mitsuo Sawamoto 10254-10257  |
| Full: PDF (491 K) |
| Branch-Selective, Iridium-Catalyzed Hydroarylation of Monosubstituted Alkenes via a Cooperative Destabilization Strategy Giacomo E. M. Crisenza, Niall G. McCreanor, and John F. Bower 10258-10261  |
| Full: PDF (1310 K) |
| Cooperative Transition Metal/Lewis Acid Bond-Activation Reactions by a Bidentate (Boryl)iminomethane Complex: A Significant Metal–Borane Interaction Promoted by a Small Bite-Angle LZ Chelate Brandon R. Barnett, Curtis E. Moore, Arnold L. Rheingold, and Joshua S. Figueroa 10262-10265  |
| Full: PDF (924 K) |
| Mild Aminoacylation of Indoles and Pyrroles through a Three-Component Reaction with Ynol Ethers and Sulfonyl Azides Joshua S. Alford and Huw M. L. Davies 10266-10269  |
| Full: PDF (800 K) |
| Synthesis of (−)-Pseudotabersonine, (−)-Pseudovincadifformine, and (+)-Coronaridine Enabled by Photoredox Catalysis in Flow Joel W. Beatty and Corey R. J. Stephenson 10270-10273  |
| Full: PDF (1216 K) |
| Total Synthesis of (−)-Crinipellin A Taek Kang, Seog Boem Song, Won-Yeob Kim, Byung Gyu Kim, and Hee-Yoon Lee 10274-10276  |
| Full: PDF (578 K) |
Articles
| Specific and Nonspecific Interactions in Ultraweak Protein–Protein Associations Revealed by Solvent Paramagnetic Relaxation Enhancements Helle Johansson, Malene Ringkjøbing Jensen, Henrik Gesmar, Sebastian Meier, Joachim M. Vinther, Camille Keeler, Michael E. Hodsdon, and Jens J. Led 10277-10286  |
| Full: PDF (4135 K) |
| First-Principles Study of Phenol Hydrogenation on Pt and Ni Catalysts in Aqueous Phase Yeohoon Yoon, Roger Rousseau, Robert S. Weber, Donghai Mei, and Johannes A. Lercher 10287-10298  |
| Full: PDF (5397 K) |
| Effects of Atomic Geometry and Electronic Structure of Platinum Surfaces on Molecular Adsorbates Studied by Gap-Mode SERS Jian Hu, Masahiro Tanabe, Jun Sato, Kohei Uosaki, and Katsuyoshi Ikeda 10299-10307  |
| Full: PDF (4963 K) |
| Photodissociation of Conformer-Selected Ubiquitin Ions Reveals Site-Specific Cis/Trans Isomerization of Proline Peptide Bonds Stephan Warnke, Carsten Baldauf, Michael T. Bowers, Kevin Pagel, and Gert von Helden 10308-10314  |
| Full: PDF (1379 K) |
| Thermodynamic Mechanism for the Evasion of Antibody Neutralization in Flaviviruses Rodrigo A. Maillard, Tong Liu, David W. C. Beasley, Alan D. T. Barrett, Vincent J. Hilser, and J. Ching Lee 10315-10324  |
| Full: PDF (4327 K) |
| Differential Control of Heme Reactivity in Alpha and Beta Subunits of Hemoglobin: A Combined Raman Spectroscopic and Computational Study Eric M. Jones, Emanuele Monza, Gurusamy Balakrishnan, George C. Blouin, Piotr J. Mak, Qianhong Zhu, James R. Kincaid, Victor Guallar, and Thomas G. Spiro 10325-10339  |
| Full: PDF (7150 K) |
| A Multi-State, Allosterically-Regulated Molecular Receptor With Switchable Selectivity Jose Mendez-Arroyo, Joaquín Barroso-Flores, Alejo M. Lifschitz, Amy A. Sarjeant, Charlotte L. Stern, and Chad A. Mirkin 10340-10348  |
| Full: PDF (3480 K) |
| Probing the Electrostatics of Active Site Microenvironments along the Catalytic Cycle for Escherichia coli Dihydrofolate Reductase C. Tony Liu, Joshua P. Layfield, Robert J. Stewart, III, Jarrod B. French, Philip Hanoian, John B. Asbury, Sharon Hammes-Schiffer, and Stephen J. Benkovic 10349-10360  |
| Full: PDF (3495 K) |
| Electronic States of the Quasilinear Molecule Propargylene (HCCCH) from Negative Ion Photoelectron Spectroscopy David L. Osborn, Kristen M. Vogelhuber, Scott W. Wren, Elisa M. Miller, Yu-Ju Lu, Amanda S. Case, Leonid Sheps, Robert J. McMahon, John F. Stanton, Lawrence B. Harding, Branko Ruscic, and W. Carl Lineberger 10361-10372  |
| Full: PDF (1867 K) |
| Mechanisms of syn-Insertion of Alkynes and Allenes into Gold–Silicon Bonds: A Comprehensive Experimental/Theoretical Study Maximilian Joost, Laura Estevez, Sonia Mallet-Ladeira, Karinne Miqueu, Abderrahmane Amgoune, and Didier Bourissou 10373-10382  |
| Full: PDF (1481 K) |
| DNA-Controlled Partition of Carbon Nanotubes in Polymer Aqueous Two-Phase Systems Geyou Ao, Constantine Y. Khripin, and Ming Zheng 10383-10392  |
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| Half-Unit-Cell α-Fe2O3 Semiconductor Nanosheets with Intrinsic and Robust Ferromagnetism Weiren Cheng, Jingfu He, Tao Yao, Zhihu Sun, Yong Jiang, Qinghua Liu, Shan Jiang, Fengchun Hu, Zhi Xie, Bo He, Wensheng Yan, and Shiqiang Wei 10393-10398  |
| Full: PDF (2088 K) |
| Water–Polysaccharide Interactions in the Primary Cell Wall of Arabidopsis thaliana from Polarization Transfer Solid-State NMR Paul B. White, Tuo Wang, Yong Bum Park, Daniel J. Cosgrove, and Mei Hong 10399-10409  |
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| Ion-Regulated Allosteric Binding of Fullerenes (C60 and C70) by Tetrathiafulvalene-Calix[4]pyrroles Christina M. Davis, Jong Min Lim, Karina R. Larsen, Dong Sub Kim, Young Mo Sung, Dani M. Lyons, Vincent M. Lynch, Kent A. Nielsen, Jan O. Jeppesen, Dongho Kim, Jung Su Park, and Jonathan L. Sessler 10410-10417  |
| Full: PDF (2738 K) |
| The Trifluoromethyl Group as a Conformational Stabilizer and Probe: Conformational Analysis of Cinchona Alkaloid Scaffolds G. K. Surya Prakash, Fang Wang, Martin Rahm, Zhe Zhang, Chuanfa Ni, Jingguo Shen, and George A. Olah 10418-10431  |
| Full: PDF (7896 K) |
| Electrochemical and Spectroelectrochemical Characterization of an Iridium-Based Molecular Catalyst for Water Splitting: Turnover Frequencies, Stability, and Electrolyte Effects Oscar Diaz-Morales, Thomas J. P. Hersbach, Dennis G. H. Hetterscheid, Joost N. H. Reek, and Marc T. M. Koper 10432-10439  |
| Full: PDF (1013 K) |
| Hydration of Gaseous m-Aminobenzoic Acid: Ionic vs Neutral Hydrogen Bonding and Water Bridges Terrence M. Chang, Satrajit Chakrabarty, and Evan R. Williams 10440-10449  |
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| Mechanistic Studies on the Substrate-Tolerant Lanthipeptide Synthetase ProcM Subha Mukherjee and Wilfred A. van der Donk 10450-10459  |
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| Very Large Cooperative Effects in Heterobimetallic Titanium-Chromium Catalysts for Ethylene Polymerization/Copolymerization Shaofeng Liu, Alessandro Motta, Aidan R. Mouat, Massimiliano Delferro, and Tobin J. Marks 10460-10469  |
| Full: PDF (2567 K) |
| Unusual Reaction of [NiFe]-Hydrogenases with Cyanide Suzannah V. Hexter, Min-Wen Chung, Kylie A. Vincent, and Fraser A. Armstrong 10470-10477  |
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| In Situ Hybridization of Superparamagnetic Iron-Biomolecule Nanoparticles Nafiseh Moghimi, Apraku David Donkor, Mamata Mohapatra, Joseph Palathinkal Thomas, Zhengding Su, Xiaowu (Shirley) Tang, and Kam Tong Leung 10478-10485  |
| Full: PDF (5250 K) |
| Length-Dependent Conductance of Oligothiophenes Brian Capozzi, Emma J. Dell, Timothy C. Berkelbach, David R. Reichman, Latha Venkataraman, and Luis M. Campos 10486-10492  |
| Full: PDF (2141 K) |
| Mechanochemistry with Metallosupramolecular Polymers Diederik W. R. Balkenende, Souleymane Coulibaly, Sandor Balog, Yoan C. Simon, Gina L. Fiore, and Christoph Weder 10493-10498  |
| Full: PDF (1953 K) |
| From Trigonal Bipyramidal to Platonic Solids: Self-Assembly and Self-Sorting Study of Terpyridine-Based 3D Architectures Ming Wang, Chao Wang, Xin-Qi Hao, Xiaohong Li, Tyler J Vaughn, Yan-Yan Zhang, Yihua Yu, Zhong-Yu Li, Mao-Ping Song, Hai-Bo Yang, and Xiaopeng Li 10499-10507  |
| Full: PDF (2644 K) |
| Strategies to Enhance Cyclopolymerization using Third-Generation Grubbs Catalyst Eun-Hye Kang, So Young Yu, In Sun Lee, Seong Eon Park, and Tae-Lim Choi 10508-10514  |
| Full: PDF (882 K) |
| Dramatically Different Kinetics and Mechanism at Solid/Liquid and Solid/Gas Interfaces for Catalytic Isopropanol Oxidation over Size-Controlled Platinum Nanoparticles Hailiang Wang, Andras Sapi, Christopher M. Thompson, Fudong Liu, Danylo Zherebetskyy, James M. Krier, Lindsay M. Carl, Xiaojun Cai, Lin-Wang Wang, and Gabor A. Somorjai 10515-10520  |
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| Uniform Doping of Metal Oxide Nanowires Using Solid State Diffusion Joaquin Resasco, Neil P. Dasgupta, Josep Roque Rosell, Jinghua Guo, and Peidong Yang 10521-10526  |
| Full: PDF (2997 K) |
| Clickable Degradable Aliphatic Polyesters via Copolymerization with Alkyne Epoxy Esters: Synthesis and Postfunctionalization with Organic Dyes Nele S. Teske, Julia Voigt, and V. Prasad Shastri 10527-10533  |
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| Regioselective Benzyl Radical Addition to an Open-Shell Cluster Metallofullerene. Crystallographic Studies of Cocrystallized Sc3C2@Ih-C80 and Its Singly Bonded Derivative Hongyun Fang, Hailin Cong, Mitsuaki Suzuki, Lipiao Bao, Bing Yu, Yunpeng Xie, Naomi Mizorogi, Marilyn M. Olmstead, Alan L. Balch, Shigeru Nagase, Takeshi Akasaka, and Xing Lu 10534-10540  |
| Full: PDF (2408 K) |
Additions and Corrections
| Correction to “Baulamycins A and B, Broad-Spectrum Antibiotics Identified as Inhibitors of Siderophore Biosynthesis in Staphylococcus aureus and Bacillus anthracis” Ashootosh Tripathi, Michael M. Schofield, George E. Chlipala, Pamela J. Schultz, Isaiah Yim, Sean A. Newmister, Tyler D. Nusca, Jamie B. Scaglione, Philip C. Hanna, Giselle Tamayo-Castillo, and David H. Sherman 10541-10541  |
| Full: PDF (171 K) |
| Correction to “Chiral Arrangement of Achiral Au Nanoparticles by Supramolecular Assembly of Helical Nanofiber Templates” Sung Ho Jung, Jiwon Jeon, Hyungjun Kim, Justyn Jaworski, and Jong Hwa Jung 10542-10542 |
| Full: PDF (119 K) |
| Correction to “Influence of Pyrazolate vs N-Heterocyclic Carbene Ligands on the Slow Magnetic Relaxation of Homoleptic Trischelate Lanthanide(III) and Uranium(III) Complexes” Katie R. Meihaus, Stefan G. Minasian, Wayne W. Lukens, Jr., Stosh A. Kozimor, David K. Shuh, Tolek Tyliszczak, and Jeffrey R. Long 10543-10543 |
| Full: PDF (125 K) |
| Correction to “Formation of Vinyl-, Vinylhalide- or Acyl-Substituted Quaternary Carbon Stereogenic Centers through NHC–Cu-Catalyzed Enantioselective Conjugate Additions of Si-Containing Vinylaluminums to β-Substituted Cyclic Enones” Tricia L. May, Jennifer A. Dabrowski, and Amir H. Hoveyda 10544-10544 |
| Full: PDF (483 K) |
| Correction to “Dynamic Introduction of Cell Adhesive Factor via Reversible Multicovalent Phenylboronic Acid/cis-Diol Polymeric Complexes” Guoqing Pan, Bingbing Guo, Yue Ma, Wenguo Cui, Fan He, Bin Li, Huilin Yang, and Kenneth J. Shea 10545-10545 |
| Full: PDF (123 K) |
| Correction to “Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses of Highly Ordered, Hydrothermally Stable, Mesoporous Silica Structures” Dongyuan Zhao, Qisheng Huo, Jianglin Feng, Bradley F. Chmelka, and Galen D. Stucky 10546-10546 |
| Full: PDF (119 K) |